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Christopher J. Gartshore and Dr. David W. Lupton Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones and Indolones: Formal Synthesis of (+)-Kopsihainanine A Angewandte Chemie International Edition 52

Article first published online: 30 JAN 2013 | DOI: 10.1002/anie.201209069

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Adding value: A four-step synthesis of enantioenriched carbazolone and indolone derivatives has been developed using an enantioselective Pd-catalyzed decarboxylative allylation. The scope of this reaction is broad, and the materials are suited for natural product synthesis, shown with the completion of a formal synthesis of (+)-kopsihainanine (see scheme).

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