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Tatsuhiko Yoshino, Hideya Ikemoto, Dr. Shigeki Matsunaga and Prof. Dr. Motomu Kanai A Cationic High-Valent Cp*CoIII Complex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation Angewandte Chemie International Edition 52

Article first published online: 16 JAN 2013 | DOI: 10.1002/anie.201209226

Active without activation: In an inexpensive and atom-economical approach to CH bond functionalization, a cationic Co^III complex (see scheme) was used to generate nucleophilic organometallic species in situ without additional activating reagents. Under these conditions, aryl CH bonds underwent efficient addition to polar electrophiles, including α,β-unsaturated N-acyl pyrroles as β-substituted ester and amide surrogates.

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