E-mail

E-mail a Wiley Online Library Link

Ying Xia, Peiyuan Qu, Zhenxing Liu, Rui Ge, Qing Xiao, Dr. Yan Zhang and Prof. Dr. Jianbo Wang Catalyst-Free Intramolecular Formal Carbon Insertion into σ-C[BOND]C Bonds: A New Approach toward Phenanthrols and Naphthols Angewandte Chemie International Edition 52

Version of Record online: 29 JAN 2013 | DOI: 10.1002/anie.201209269

Thumbnail image of graphical abstract

The different reactivity of two kinds of carbonyl groups in keto aldehyde substrates has been exploited for the synthesis of phenanthrols, naphthols, and their heteroatom-containing analogues. Key to this highly efficient and robust methodology is the catalyst-free intramolecular formal diazo carbon insertion of N-tosylhydrazones into keto C[BOND]C bonds (see scheme).

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH