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Robert Hayes, Dr. Silvia Imberti, Prof. Gregory G. Warr and Assoc. Prof. Rob Atkin The Nature of Hydrogen Bonding in Protic Ionic Liquids Angewandte Chemie International Edition 52

Article first published online: 28 FEB 2013 | DOI: 10.1002/anie.201209273

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The size, direction, strength, and distribution of hydrogen bonds in several protic ionic liquids (PILs) has been elucidated using neutron diffraction and computer simulation. There is significant variation in PIL hydrogen bond interactions ranging from short and linear to long and bi-/trifurcated. The nature of the PIL's hydrogen bonds reflects its macroscopic properties.

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