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Dr. Mikhail V. Butovskiy, Dr. Gábor Balázs, Dr. Michael Bodensteiner, Dr. Eugenia V. Peresypkina, Dr. Alexander V. Virovets, Dr. Jörg Sutter and Prof. Dr. Manfred Scheer Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry Angewandte Chemie International Edition 52

Article first published online: 31 JAN 2013 | DOI: 10.1002/anie.201209329

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Pentaphosphaferrocene redox chemistry: Unprecedented dianionic and P[BOND]P coupled and monomeric products are obtained by the reduction of pentaphosphaferrocene with KH or K metal, whereas by oxidation a P[BOND]P coupled P102+ ligand coordinated to two Cp*Fe units is obtained. The redox behavior clearly distinguishes pentaphosphaferrocene from its organometallic relative, ferrocene.

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