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Dr. Anton V. Gulevich and Prof. Dr. Vladimir Gevorgyan Versatile Reactivity of Rhodium–Iminocarbenes Derived from N-Sulfonyl Triazoles Angewandte Chemie International Edition 52

Version of Record online: 7 JAN 2013 | DOI: 10.1002/anie.201209338

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The migrations of different groups to the metal–carbene center of RhII-stabilized iminocarbenes that were derived from N-sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh-iminocabenes can be tuned easily by variation of substituents on the parent triazole.

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