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Jörn Bruns, Prof. Dr. Thorsten Klüner and Prof. Dr. Mathias S. Wickleder Bis(tetrasulfato)palladate, [Pd(S4O13)2]2− Angewandte Chemie International Edition 52

Article first published online: 29 JAN 2013 | DOI: 10.1002/anie.201209346

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SOS: The first coordination compound containing polysulfate ligands was obtained under harsh conditions from the reaction of K2[PdCl4] and SO3. The compound contains a Pd2+ ion coordinated by two chelating tetrasulfate anions (see structure, Pd red, S yellow, O blue), which leads to a significant stabilization of the polysulfate anions compared to their uncoordinated analogues.

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