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Ya-Min Li, Meng Sun, Hong-Li Wang, Qiu-Ping Tian and Prof. Shang-Dong Yang Direct Annulations toward Phosphorylated Oxindoles: Silver-Catalyzed Carbon-Phosphorus Functionalization of Alkenes Angewandte Chemie International Edition 52

Article first published online: 25 FEB 2013 | DOI: 10.1002/anie.201209475

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Silver screen: The AgNO3-catalyzed carbon phosphorylation of alkenes occurs by an alkene addition/cyclization cascade. Ag+ reacts with Ph2P(O)H to form the crucial active intermediate 1, which promotes the reaction. This method requires a cheap, nontoxic silver salt as the catalyst and substrates for the transformation are simple and readily accessible.

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