E-mail a Wiley Online Library Link

Dr. Le Du, Prof. Dr. Peng Cao, Dr. Junwei Xing, Yazhou Lou, Liyin Jiang, Dr. Liangchun Li and Prof. Dr. Jian Liao Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands Angewandte Chemie International Edition 52

Article first published online: 5 MAR 2013 | DOI: 10.1002/anie.201209485

Thumbnail image of graphical abstract

A DYKAT die hard: A new class of chiral BiSO-P ligands were effective for an unprecedented palladium-catalyzed asymmetric allylic alkylation of indoles with the racemic title acetates through a dynamic kinetic asymmetric transformation (DYKAT). The hydrogen bond formed between the sulfinyl group of the ligand and NH of indole plays an important role in the reaction.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field