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Dr. Tomoya Miura, Takamasa Tanaka, Tsuneaki Biyajima, Dr. Akira Yada and Prof. Dr. Masahiro Murakami One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes through N-Sulfonyl-1,2,3-Triazole Intermediates Angewandte Chemie International Edition 52

Article first published online: 25 FEB 2013 | DOI: 10.1002/anie.201209603

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Triple strike: Copper(I) and rhodium(II) complexes can cooperate to facilely convert terminal alkynes into α-allyl-α-amino ketones through triazole intermediates. This synthetic process achieves the regioselective multifunctionalization of terminal alkynes with the formation of C[BOND]C, C[BOND]O, and C[BOND]N bonds in one pot.

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