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Salvatore Zarra, Dr. Jack K. Clegg and Dr. Jonathan R. Nitschke Selective Assembly and Disassembly of a Water-Soluble Fe10L15 Prism Angewandte Chemie International Edition 52

Article first published online: 26 FEB 2013 | DOI: 10.1002/anie.201209694

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Survival of the fittest: Two water-soluble metal–organic architectures, a tetrahedron and a pentagonal prism, were selectively assembled from the same building blocks under different reaction conditions. In a mixture of the two, the prism was disassembled upon addition of 4-methoxyaniline to form a mononuclear complex, while leaving the more stable tetrahedral structure intact.

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