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Samuel P. Black, Dr. Artur R. Stefankiewicz, Dr. Maarten M. J. Smulders, Dominik Sattler, Prof. Christoph A. Schalley, Dr. Jonathan R. Nitschke and Prof. Jeremy K. M. Sanders Generation of a Dynamic System of Three-Dimensional Tetrahedral Polycatenanes Angewandte Chemie International Edition 52

Article first published online: 18 APR 2013 | DOI: 10.1002/anie.201209708

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Seven of the best: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe4L6 tetrahedral cage, constructed from ligands containing an electron-deficient naphthalenediimide core, and an electron-rich aromatic crown ether, 1,5-dinaphtho[38]crown-10. The highest order species in the library is the tetrahedral [7]catenane.

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