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Prof. Dr. Holger Braunschweig, Dr. Peter Brenner, Dr. Rian D. Dewhurst, Dr. J. Oscar C. Jimenez-Halla, Dr. Thomas Kupfer, Dr. Daniela Rais and Dr. Katharina Uttinger Maximizing Coordinative and Electronic Unsaturation: Three-Coordinate Dicationic Platinum Complexes Angewandte Chemie International Edition 52

Article first published online: 31 JAN 2013 | DOI: 10.1002/anie.201209717

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Halide abstraction from cationic base-stabilized borylene complexes led to extremely electronically and coordinatively unsaturated platinum complexes. The formally 14-electron borylene complexes show no agostic interactions with the phosphine ligands, and only small Lewis donor ligands could be added to the Pt center.

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