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Prof. Barry M. Trost, James T. Masters and Dr. Aaron C. Burns Palladium-Catalyzed Asymmetric Allylic Alkylation of 3-Aryloxindoles with Allylidene Dipivalate: A Useful Enol Pivalate Product Angewandte Chemie International Edition 52

Version of Record online: 17 JAN 2013 | DOI: 10.1002/anie.201209783

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Triple A: The catalytic asymmetric allylic alkylation (AAA) of 3-aryloxindoles with allylidene dipivalate is described. This reaction affords stable, synthetically useful enol pivalates in high yield and with excellent regio- and enantioselectivity. A broad range of substrates is tolerated, including unprotected and 3-heteroaryl nucleophiles.

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