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Liangcan He, Yong Liu, Jingzhu Liu, Yansong Xiong, Jianzhong Zheng, Prof. Yaling Liu and Prof. Zhiyong Tang Core–Shell Noble-Metal@Metal-Organic-Framework Nanoparticles with Highly Selective Sensing Property Angewandte Chemie International Edition 52

Version of Record online: 18 FEB 2013 | DOI: 10.1002/anie.201209903

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Of cores! Core–shell Au@metal-organic-framework-5 (MOF-5) nanoparticles (NPs), in which a single Au NP core is coated with a uniform MOF-5 shell, were prepared by a facile one-pot method. The diameter of the Au NP core and the thickness of the MOF-5 shell are easily tuned by controlling the reaction conditions. These nanoparticles are selective sensors of CO2 in gas mixtures.

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