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Long Wang, He Huang, Dr. Daniel L. Priebbenow, Fang-Fang Pan and Prof. Dr. Carsten Bolm Copper-Catalyzed Oxidative Cross-Coupling of Sulfoximines and Alkynes Angewandte Chemie International Edition 52

Version of Record online: 12 FEB 2013 | DOI: 10.1002/anie.201209975

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A 'Cu'te couple: A synthetically useful protocol for the preparation of N-alkynylated sulfoximines (yne sulfoximines) has been developed. The method involves a mild copper-catalyzed oxidative cross-coupling of NH-sulfoximines and terminal alkynes (see scheme). The corresponding N-acyl sulfoximines were also obtained selectively after acid-catalyzed hydrolysis of the yne sulfoximines.

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