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Alexander Gmehling, Wolfgang Donaubauer, Dr. Frank Hampel, Dr. Frank W. Heinemann and Prof. Dr. Andreas Hirsch Invertomers of Fullerenophosphates Angewandte Chemie International Edition 52

Version of Record online: 12 FEB 2013 | DOI: 10.1002/anie.201209981

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The ins and outs of fullerene chemistry: Fullerenophosphates with a C3-symmetrical e,e,e-trisaddition pattern were synthesized with high regioselectivity. In- (see structure, red O, yellow P, blue C) and out-invertomers, based on the orientation of the P[DOUBLE BOND]O group, were isolated and their structures were confirmed by X-ray-crystallography.

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