E-mail

E-mail a Wiley Online Library Link

Dr. Azusa Iida, Dr. Shohei Saito, Prof. Dr. Takahiro Sasamori and Prof. Dr. Shigehiro Yamaguchi Borylated Dibenzoborepin: Synthesis by Skeletal Rearrangement and Photochromism Based on Bora-Nazarov Cyclization Angewandte Chemie International Edition 52

Article first published online: 20 FEB 2013 | DOI: 10.1002/anie.201210236

Thumbnail image of graphical abstract

It's a boron kind of magic: A complex reaction sequence involving a skeletal rearrangement leads to 10-dimesitylboryl-substituted dibenzoborepin in a one-pot transformation in good yield. The borylborepin shows remarkable photochromic properties and undergoes a bora-Nazarov cyclization to give a deep-blue compound with an allyl cation-like C[BOND]B[BOND]C substructure.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH