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Dr. Atsushi Nagai, Xiong Chen, Xiao Feng, Xuesong Ding, Dr. Zhaoqi Guo and Prof. Dr. Donglin Jiang A Squaraine-Linked Mesoporous Covalent Organic Framework Angewandte Chemie International Edition 52

Version of Record online: 21 FEB 2013 | DOI: 10.1002/anie.201300256

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π in the sky: A squaraine-linked, conjugated two-dimensional porphyrin covalent organic framework (COF; see scheme; C: gray, H: white, N: blue, Cu: red) was synthesized. Owing to the π-conjugated linkage together with the eclipsed stacking of the units, this COF exhibits enhanced chemical and thermal stabilities. It absorbs a broad range of light, from the ultraviolet to the visible, and near-infrared regions, and shows potential as a photocatalyst.

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