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Tzu-Pin Lin and Prof. Dr. François P. Gabbaï Telluronium Ions as σ-Acceptor Ligands Angewandte Chemie International Edition 52

Version of Record online: 18 FEB 2013 | DOI: 10.1002/anie.201300337

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A duel between lone pairs: A telluronium cation has been successfully installed in the coordination sphere of a palladium(II) complex. Despite the presence of a lone pair centered on the Group 16 element, the telluronium ion acts as a Z-ligand and accepts a d-electron pair from the palladium atom.

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