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Dr. Sudheendran Mavila, Dr. Charles E. Diesendruck, Sivan Linde, Liron Amir, Dr. Rafi Shikler and Prof. Dr. N. Gabriel Lemcoff Polycyclooctadiene Complexes of Rhodium(I): Direct Access to Organometallic Nanoparticles Angewandte Chemie International Edition 52

Article first published online: 19 MAR 2013 | DOI: 10.1002/anie.201300362

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Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C2H4)2}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

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