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Dr. Vincent Coeffard, Dr. Xavier Moreau, Dr. Christine Thomassigny and Prof. Christine Greck Transition-Metal-Free Amination of Aryl boronic Acids and Their Derivatives Angewandte Chemie International Edition 52

Article first published online: 19 APR 2013 | DOI: 10.1002/anie.201300382

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Free rein: Advances in transition-metal-free direct amination of aryl boronic acids and their derivatives have been recently described (see scheme). These reactions are based on the use of hydroxylamine or azide derivatives and offer great potential for further applications.

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