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Lydia C. Gilday, Dr. Thomas Lang, Dr. Antonio Caballero, Dr. Paulo J. Costa, Prof. Vítor Félix and Prof. Paul D. Beer A Catenane Assembled through a Single Charge-Assisted Halogen Bond Angewandte Chemie International Edition 52

Article first published online: 11 MAR 2013 | DOI: 10.1002/anie.201300464

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Getting connected: The formation of pseudorotaxane assemblies between a designed macrocyclic halogen bonding (XB) acceptor (red in scheme) and a series of XB donor threading components was templated by a single halogen bond. The strength of the XB assembly between the pyridine macrocycle and iodopyridinium thread was utilized in the ring-closing metathesis clipping synthesis of a [2]catenane.

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