Dr. Mike Ahrens, Priv.-Doz. Dr. Gudrun Scholz, Prof. Dr. Thomas Braun and Prof. Dr. Erhard Kemnitz Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species Angewandte Chemie International Edition 52
'Al'l about F: Aluminum chlorofluoride (ACF) catalyzes the hydrodefluorination, as well as Friedel–Crafts reactions of fluorinated methanes in the presence of Et3SiH. A surface-bound silylium-ion-like species is considered to be a crucial intermediate in achieving the CF bond cleavage.
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