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Jiliang Zhou, Jiaxiang Chu, Yanyan Zhang, Guang Yang, Dr. Xuebing Leng and Prof. Dr. Yaofeng Chen An Yttrium Hydride–Silane Complex as a Structural Model for a σ-Bond Metathesis Transition State Angewandte Chemie International Edition 52

Article first published online: 7 MAR 2013 | DOI: 10.1002/anie.201300638

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A structural model for the transition state of the σ-bond metathesis between Si[BOND]H and M[BOND]E bonds (M: d0 transition metal) was obtained through the formation of an yttrium hydride–silane complex (see picture). The silane moiety can be either retained or released during the reactions of the complex with other substrates.

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