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Javix Thomas, Dr. Oleksandr Sukhorukov, Prof. Dr. Wolfgang Jäger and Prof. Dr. Yunjie Xu Chirped-Pulse and Cavity-Based Fourier Transform Microwave Spectra of the Methyl Lactate⋅⋅⋅Ammonia Adduct Angewandte Chemie International Edition 52

Version of Record online: 14 MAR 2013 | DOI: 10.1002/anie.201300707

Thumbnail image of graphical abstract

Internal rotations: Using a broadband chirped-pulse and a cavity-based microwave spectrometer, the delicate balance between intra- and intermolecular hydrogen-bonding interactions in the methyl lactate⋅⋅⋅NH3 adduct was investigated (see picture). The adduct is a prototype lock-and-key system consisting of a lock with two “spinning” tops and a key which is also a spinning top itself.

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