E-mail a Wiley Online Library Link

Paweł Dydio and Prof. Dr. Joost N. H. Reek Back Cover: Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates (Angew. Chem. Int. Ed. 14/2013) Angewandte Chemie International Edition 52

Version of Record online: 4 MAR 2013 | DOI: 10.1002/anie.201301447

Thumbnail image of graphical abstract

Precise selectivity control in transition-metal catalysis is critical for modern chemical synthesis. In their Communication on page 3878 ff., J. N. H. Reek and P. Dydio demonstrate that substrate preorganization through noncovalent supramolecular interactions with the ligand is a powerful enabling strategy to control selectivity, and gives access to usually unfavored products. As exemplified for the Rh-catalyzed hydroformylation of vinyl arenes, this approach opens up new avenues in the synthesis of valuable compounds.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field