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Beatrice S. L. Collins, Dr. Marcos G. Suero and Prof. Matthew J. Gaunt Copper-Catalyzed Arylative Meyer–Schuster Rearrangement of Propargylic Alcohols to Complex Enones Using Diaryliodonium Salts Angewandte Chemie International Edition 52

Version of Record online: 22 APR 2013 | DOI: 10.1002/anie.201301529

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Free choice: A copper-catalyzed arylative Meyer–Schuster rearrangement is described. The reaction is compatible with a range of substituted propargylic alcohols and diaryliodonium salts and delivers complex trisubstituted enone products selectively as the E isomers.

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