Manuel Jäger, Marcel Hartmann, Prof. Dr. Johannes G. de Vries and Prof. Dr. Adriaan J. Minnaard Catalytic Regioselective Oxidation of Glycosides Angewandte Chemie International Edition 52
Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates.
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