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Manuel Jäger, Marcel Hartmann, Prof. Dr. Johannes G. de Vries and Prof. Dr. Adriaan J. Minnaard Catalytic Regioselective Oxidation of Glycosides Angewandte Chemie International Edition 52

Version of Record online: 18 JUN 2013 | DOI: 10.1002/anie.201301662

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Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates.

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