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Dr. Edyta Burda, Tina Reß, Till Winkler, Carolin Giese, Xenia Kostrov, Tobias Huber, Prof. Dr. Werner Hummel and Prof. Dr. Harald Gröger Highly Enantioselective Reduction of α-Methylated Nitroalkenes Angewandte Chemie International Edition 52

Version of Record online: 26 JUL 2013 | DOI: 10.1002/anie.201301814

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Highly selective: The reduction of α-methyl-substituted nitroalkenes succeeds in a highly enantioselective fashion with an ene reductase from Gluconobacter oxydans. Under optimized reaction conditions the desired nitroalkanes are formed with enantiomeric excesses of up to 95% in these biotransformations.

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