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Dr. Matteo Farnesi Camellone, Dr. Jianli Zhao, Lanying Jin, Dr. Yuemin Wang, Prof. Dr. Martin Muhler and Prof. Dr. Dominik Marx Molecular Understanding of Reactivity and Selectivity for Methanol Oxidation at the Au/TiO2 Interface Angewandte Chemie International Edition 52

Version of Record online: 15 APR 2013 | DOI: 10.1002/anie.201301868

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Gold catalysis: Experimental and theoretical data demonstrated consistently that the interfacial sites on a Au/TiO2 catalyst show both high reactivity and selectivity for low-temperature methanol oxidation with O2 to give formaldehyde. The microscopic mechanism of this complex reaction has been unraveled in full molecular detail (see picture, gold cluster on TiO2 surface).

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