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Ken Mukai, Dr. Daisuke Urabe, Dr. Satoshi Kasuya, Naoto Aoki and Prof. Dr. Masayuki Inoue A Convergent Total Synthesis of 19-Hydroxysarmentogenin Angewandte Chemie International Edition 52

Article first published online: 15 APR 2013 | DOI: 10.1002/anie.201302067

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19 in 19: A convergent total synthesis of 19-hydroxysarmentogenin has been achieved, starting from three simple fragments. The desired product was synthesized in 19 steps from the AB ring system with the installation of six stereocenters and the formation of three C[BOND]C bonds.

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