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Xiaoshi Wang, Sebastian Peter, Dr. René Ullrich, Prof. Martin Hofrichter and Prof. John T. Groves Driving Force for Oxygen-Atom Transfer by Heme-Thiolate Enzymes Angewandte Chemie International Edition 52

Version of Record online: 3 JUL 2013 | DOI: 10.1002/anie.201302137

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Absolutely: Redox potentials for three redox couples in AaeAPO-catalyzed reactions have been measured, thus placing these heme-thiolate reactive intermediates on an absolute energy scale for the first time. The importance of the axial thiolate ligand and the basic nature of compound II ferryl oxygen atom are discussed in terms of these redox potentials.

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