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Xiaocun Lu, Prof. Xiaopeng Li, Dr. Yan Cao, Dr. Anthony Schultz, Dr. Jin-Liang Wang, Dr. Charles N. Moorefield, Prof. Chrys Wesdemiotis, Prof. Stephen Z. D. Cheng and Prof. George R. Newkome Self-Assembly of a Supramolecular, Three-Dimensional, Spoked, Bicycle-like Wheel Angewandte Chemie International Edition 52

Version of Record online: 13 JUN 2013 | DOI: 10.1002/anie.201302362

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Where there′s a wheel, there′s a way: The terpyridine-based title system has been synthesized through a facile self-assembly process. Two tris(terpyridine) ligands possessing angles of either 120° or 60° between adjacent tpy units were mixed with a stoichiometric amount of Zn2+ (2:6:12) to generate the desired coordination-driven bicycle-like wheel (90 % yield).

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