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Xavier Just-Baringo, Dr. Paolo Bruno, Dr. Lars K. Ottesen, Dr. Librada M. Cañedo, Prof. Fernando Albericio and Prof. Mercedes Álvarez Total Synthesis and Stereochemical Assignment of Baringolin Angewandte Chemie International Edition 52

Version of Record online: 18 JUN 2013 | DOI: 10.1002/anie.201302372

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The thiopeptide antibiotic baringolin has been synthesized, and its structure and stereochemistry have been confirmed. The use of a strategy based on palladium-catalyzed cross-couplings permitted a modular construction of this natural product.

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