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Gaocan Li, Shengyou Qian, Chunxia Wang and Prof. Dr. Jingsong You Palladium(II)-Catalyzed Dehydrogenative Cross-Coupling between Two C sp 3[BOND]H Bonds: Unexpected C[DOUBLE BOND]C Bond Formation Angewandte Chemie International Edition 52

Version of Record online: 18 JUN 2013 | DOI: 10.1002/anie.201303099

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C[DOUBLE BOND]C bond construction: A palladium-catalyzed oxidative Cmath image[BOND]H/Cmath image[BOND]H cross-coupling is shown to forge C[DOUBLE BOND]C bonds rather than Cmath image[BOND]Cmath image bonds through reactions of indolin-2-ones or benzofuran-2-ones with O-benzoyl hydroxylamines in the absence of an added oxidant.

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