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Dr. Iker León, Dr. Judith Millán, Dr. Emilio J. Cocinero, Prof. Alberto Lesarri and Dr. José A. Fernández Shaping Micelles: The Interplay Between Hydrogen Bonds and Dispersive Interactions Angewandte Chemie International Edition 52

Version of Record online: 10 JUN 2013 | DOI: 10.1002/anie.201303245

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A subtle interplay: In the formation of a 1.6 nm micelle containing up to six molecules of propofol, a hydrogen-bond network is shown to influence the structure of the micelle, whereas the nonpolar groups arrange in such a way that the remaining noncovalent interactions are maximized. Such globular structures present a characteristic signature in the IR spectrum that will allow their identification in more complex media.

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