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Dr. Hiromichi Egami, Dr. Shintaro Kawamura, Dr. Ayako Miyazaki and Prof. Dr. Mikiko Sodeoka Trifluoromethylation Reactions for the Synthesis of β-Trifluoromethylamines Angewandte Chemie International Edition 52

Article first published online: 13 JUN 2013 | DOI: 10.1002/anie.201303350

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A multitalented system: N-Migratory oxytrifluoromethylation and one-pot three-component reactions of allylamines as well as the aminotrifluoromethylation of alkenyl amines all proceeded efficiently in the presence of the Togni reagent (1) and CuI to afford a variety of β-trifluoromethylamine derivatives (see scheme).

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