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Chong Qin, Peng Feng, Yang Ou, Tao Shen, Teng Wang and Dr. Ning Jiao Selective C sp 2[BOND]Csp Bond Cleavage: The Nitrogenation of Alkynes to Amides Angewandte Chemie International Edition 52

Version of Record online: 26 JUN 2013 | DOI: 10.1002/anie.201303376

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Breakthrough: A novel catalyzed direct highly selective Cmath image[BOND]Csp bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective Cmath image[BOND]Csp bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.

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