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Marc Garcia-Borràs, Dr. Sílvia Osuna, Prof. Marcel Swart, Dr. Josep M. Luis and Prof. Miquel Solà Maximum Aromaticity as a Guiding Principle for the Most Suitable Hosting Cages in Endohedral Metallofullerenes Angewandte Chemie International Edition 52

Article first published online: 10 JUL 2013 | DOI: 10.1002/anie.201303636

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Encapsulating! The encapsulation of metal clusters in endohedral metallofullerenes takes place in cages that, in most cases, are far from being the most stable isomer in the corresponding hollow fullerenes. In contrast to previous proposals, new results indicate that it is the maximum aromaticity criterion that determines the most suitable hosting cages.

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