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Dr. Koichi Fumino, B. Sc. Peter Stange, M. Sc. Verlaine Fossog, Prof. Dr. Rolf Hempelmann and Prof. Dr. Ralf Ludwig Equilibrium of Contact and Solvent-Separated Ion Pairs in Mixtures of Protic Ionic Liquids and Molecular Solvents Controlled by Polarity Angewandte Chemie International Edition 52

Article first published online: 2 OCT 2013 | DOI: 10.1002/anie.201303944

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Polarity controls the equilibrium constants and free energies of contact ion pairs (CIPs) and solvent-separated ion pairs (SIPs) in mixtures of protic ionic liquids and molecular solvents. The subtle balance between the ionic species was studied by far-infrared difference spectra and related DFT-calculated properties for solvents of low and high polarity and for different solvent concentrations.

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