Dr. Koichi Fumino, B. Sc. Peter Stange, M. Sc. Verlaine Fossog, Prof. Dr. Rolf Hempelmann and Prof. Dr. Ralf Ludwig Equilibrium of Contact and Solvent-Separated Ion Pairs in Mixtures of Protic Ionic Liquids and Molecular Solvents Controlled by Polarity Angewandte Chemie International Edition 52
Polarity controls the equilibrium constants and free energies of contact ion pairs (CIPs) and solvent-separated ion pairs (SIPs) in mixtures of protic ionic liquids and molecular solvents. The subtle balance between the ionic species was studied by far-infrared difference spectra and related DFT-calculated properties for solvents of low and high polarity and for different solvent concentrations.
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