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Changcheng Jing, Dr. Dong Xing, Yu Qian, Taoda Shi, Yun Zhao and Prof. Dr. Wenhao Hu Diversity-Oriented Three-Component Reactions of Diazo Compounds with Anilines and 4-Oxo-Enoates Angewandte Chemie International Edition 52

Article first published online: 3 JUL 2013 | DOI: 10.1002/anie.201303987

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Choosing a path: The title reaction can proceed through two different reaction pathways, and is controlled by the addition sequence of the substrates. Divergent polyfunctional products, pyrrolidines or linear α-amino ester derivatives, are obtained in good yields and high diastereoselectivities.

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