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Dr. Chandra Kanta De, Dr. Fabio Pesciaioli and Prof. Dr. Benjamin List Catalytic Asymmetric Benzidine Rearrangement Angewandte Chemie International Edition 52

Article first published online: 5 JUL 2013 | DOI: 10.1002/anie.201304039

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A chiral Brønsted acid catalyzes the asymmetric benzidine rearrangement of N,N′-dinaphthylhydrazines. Different electronically and structurally diverse axially chiral 2,2′-binaphthyl diamine (BINAM) derivatives are obtained with high enantioselectivity.

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