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Prof. Dr. Hitoshi Shindo, Yusuke Shirota, Kaori Niki, Prof. Dr. Tsuneomi Kawasaki, Dr. Kenta Suzuki, Yuko Araki, Dr. Arimasa Matsumoto and Prof. Dr. Kenso Soai Asymmetric Autocatalysis Induced by Cinnabar: Observation of the Enantioselective Adsorption of a 5-Pyrimidyl Alkanol on the Crystal Surface Angewandte Chemie International Edition 52

Version of Record online: 23 JUL 2013 | DOI: 10.1002/anie.201304284

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A chiral mineral, cinnabar, served as a chiral source of asymmetric autocatalysis to afford enantioenriched 5-pyrimidyl alkanol. The adsorption structures of related compounds were observed with atomic force microscopy. Enantioselective adsorption of the asymmetric autocatalyst was found in microcrystal formations at the chiral surface of cinnabar.

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