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M. Sc. Amou Akhgarnusch, Dr. Robert F. Höckendorf, Dr. Qiang Hao, K. Philip Jäger, Dr. Chi-Kit Siu and Prof. Dr. Martin K. Beyer Inside Cover: Carboxylation of Methyl Acrylate by Carbon Dioxide Radical Anions in Gas-Phase Water Clusters (Angew. Chem. Int. Ed. 35/2013) Angewandte Chemie International Edition 52

Article first published online: 19 JUL 2013 | DOI: 10.1002/anie.201305676

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Electron transfer turns the chemically inert CO2 molecule into a reactive radical anion. In their Communication on page 9327 ff., C.-K. Siu, M. K. Beyer, and co-workers show how CO2.−, stabilized in a water cluster, attacks the C[DOUBLE BOND]C bond of methyl acrylate to form a new covalent bond. Without the hydration shell, however, neutral CO2 is released.

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