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Zhibin Shu, Yuxuan Ye, Yifan Deng, Dr. Yan Zhang and Prof. Dr. Jianbo Wang Palladium(II)-Catalyzed Direct Conversion of Methyl Arenes into Aromatic Nitriles Angewandte Chemie International Edition 52

Article first published online: 21 AUG 2013 | DOI: 10.1002/anie.201305731

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From methyl to nitrile: A mild ammoxidation method, which directly converts methyl arenes into aromatic nitriles, has been developed by using Pd(OAc)2 and N-hydroxyphthalimide (NHPI) as the catalysts, and tert-butyl nitrite as the nitrogen source and oxidant.

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