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Dr. Aiko Fukazawa, Daisuke Kishi, Yuki Tanaka, Prof. Dr. Shu Seki and Prof. Dr. Shigehiro Yamaguchi Diarylated Bi(thieno[2,3-c]thiophene)s: A Ring-Fusing Strategy for Controlling the Molecular Alignment of Oligoarenes Angewandte Chemie International Edition 52

Version of Record online: 20 SEP 2013 | DOI: 10.1002/anie.201306323

Thumbnail image of graphical abstract

Red means go: The dense π stacking of thiophene-fused bithiophene derivatives in the crystalline state led to significantly red-shifted absorption and fluorescence bands (see the photograph of one compound in solution and in the solid state under UV irradiation). The π-stacking structure could be altered by changing the orientation of one of the fused thiophene rings.

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