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Dr. Tiffany Piou, Ala Bunescu, Dr. Qian Wang, Dr. Luc Neuville and Prof. Dr. Jieping Zhu Palladium-Catalyzed Through-Space C(sp3)[BOND]H and C(sp2)[BOND]H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles Angewandte Chemie International Edition 52

Version of Record online: 17 SEP 2013 | DOI: 10.1002/anie.201306532

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Palladium two step: Linear anilides were converted into the title compounds in good to excellent yields through a palladium-catalyzed domino carbopalladation/1,4-palladium shift sequence. The C(sp3)-H activation involves a seven-membered palladacycle, and is chemoselective in the presence of competitive C(sp2)[BOND]H bonds. DMA=N,N-dimethylacetamide, OPiv=pivalate.

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