Tongdao Wang, Dr. Jun Zhu, Feifei Han, Chen Zhou, Hanyu Chen, Dr. Hong Zhang and Prof. Dr. Haiping Xia Synthesis of Five-Membered Osmacycloallenes and Conversion into Six-Membered Osmacycloallenes Angewandte Chemie International Edition 52
Highly stable five-membered metallacycloallenes were synthesized under mild conditions. Calculations revealed that the incorporation of transition-metal moieties relieves considerable strain and indicates a trend toward ring enlargement in the five-membered metallacycloallenes. Conversion into six-membered metallacycloallenes was confirmed experimentally.
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