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Satoshi Shibata, Dr. Tomoyoshi Suenobu and Prof. Dr. Shunichi Fukuzumi Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen by Using a Water-Soluble Iridium Complex and Flavin Mononucleotide Angewandte Chemie International Edition 52

Article first published online: 25 OCT 2013 | DOI: 10.1002/anie.201307273

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H2, O2 to H2O2: The direct synthesis of hydrogen peroxide from hydrogen and oxygen in water has been made possible by using an iridium(III) complex, [IrIII(Cp*)(4-(1H-pyrazol-1-yl-κN2)benzoic acid-κC3)(H2O)]2SO4, and flavin mononucleotide. This method gives hydrogen peroxide with a high turnover number (847) and yield (19.2 %) under normal pressure and at room temperature.

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